Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat Metal Complexes of Biologically Important Ligands, CLI [1]. Organometallic Complexes of R-3-(3-Pyridyl)alaninate
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چکیده
Reactions of chloro bridged complexes with R-3-(3-pyridyl)alanine afford the chelate complexes LnM[NH2CH(CO2)CH2C5H4NH+]Cl− (LnM = Ph3P(Cl)Pd, (tol3P)(Cl)Pd, (Ph-pyridyl)2Ir, Cp∗(Cl)Rh, Cp∗(Cl)Ir, (p-Cymol)(Cl)Ru) with protonated pyridine substituents. An analogous Cp∗Rh complex with 3-(2-pyridyl)alaninate was also obtained. Addition of base (NaOMe) to these complexes gives dimeric and trimeric complexes with coordination of the pyridine N atom.
منابع مشابه
Metallkomplexe mit biologisch wichtigen Liganden, XLII [1] Carbonylmetallkomplexe mit Anionen von mehrfunktionellen «-Aminosäuren Metal Complexes with Biologically Important Ligands, X L II [1] Carbonyl Metal Complexes with Anions of Polyfunctional a-Amino Acids
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